Solid hydrocarbons Cleanly converting coal, petroleum coke and biomass into highvalue products and power. Air Products' gasification process converts coal, petcoke and biomass into highvalue products. Demand for coal is increasing because of the world's growing appetite for energy. However, depletion of the highestquality deposits and ...
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Although there are a number of different demonstrated process routes for production of liquid fuels from solid feedstocks like coal ( direct coal liquefaction), the most important methods have based on production of syngas from gasification of coal, which is converted to liquid hydrocarbons or alcohol for use as fuel or fuel refining feedstock.
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We claim: 1. A continuous two reactor stage coal conversion process for catalytic hydrogenation of coal particles and subsequent liquefaction thereof for producing coalderived hydrocarbon liquid and gas products, said process comprising: (a) mixing solid coal particles having particle size ranging from about 20 mesh to about 400 mesh ( Sieve Series) with hydrocarbon liquid solvent in a ...
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Indirect liquefaction requires an intermediate gasification of the solid coal to form a synthesis gas, which is then converted to the liquid product. This process results in the complete dismantling of the coal structure. direct liquefaction, coal is exposed directly to hydrogen at high temperatures (450C) and high pressures (kPa ...
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The process which converts solid coal into liquid hydrocarbon fuel is known as coal liquifaction. The liquefaction converts solid coal directly into liquid form with no intermediate step. Suggest Corrections. 0.
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Conversion. In general, coal can be considered a hydrogendeficient hydrocarbon with a hydrogentocarbon ratio near, as compared with a liquid hydrocarbons ratio near 2 (for propane, ethane, butane, and other forms of natural gas) and a gaseous hydrocarbons ratio near 4 (for gasoline).
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a gasification plant for converting solid or liquid hydrocarbon fuels into synthesis gas (syngas) 3. a syngas gas cleanup system and. 4. ... of mineral matter suitability are supported by laboratory and technical scale measurements of specific aspects of the coal conversion process.
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Coal rank through vitrinite reflectance can be used to determine the potential of a coal seam for producing hydrocarbons. ... The liquid yield and the nature of solid residue from coals of constant coal rank ... An understanding of the effect of maceral composition during coal conversion process is essential as the variation in its physical and ...
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Mar 15 2013. The FischerTropsch (FT) process, originally developed by Franz Fischer and Hans Tropsch in early 1920s, is a series of chemical reactions that involve the conversion of hydrogen and carbon monoxide into liquid hydrocarbons by using a catalyst. This process is a key component of gas to liquid technology.
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4 Liquefaction. Coal liquefaction is the process of making a liquid fuel from coal. The fundamental difference between coal, a solid, and liquid fuels is that the liquid fuels have a higher hydrogen:carbon ratio. Liquid fuels have lower ash contents and are easier to upgrade (, to remove unwanted impurities such as nitrogen and sulfur).
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It can convert biomass into fuel gas, liquid oil, and solid coal efficiently in the absence of oxygen [86,87], which occurs at relatively low temperatures (between 350 and 700 °C). This process involves the heating and drying of a biomass particle, as well as the release of volatiles.
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The coal is converted into a complex mixture of gaseous hydrocarbons with heat values ranging from 100 Btu to 1000 Btu. One suggestion has been to construct gasification systems within a coal mine, making it much easier to remove the coal (in a gaseous form) from its original seam. In the process of liquefaction, solid coal is converted to a ...
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Coal liquefaction is a process of converting coal into liquid hydrocarbons: liquid fuels and process is often known as "Coal to X" or "Carbon to X", where X can be many different hydrocarbonbased products. However, the most common process chain is "Coal to Liquid Fuels" (CTL).
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The indirect route is composed of 2 steps: First, coal is gasified with steam and oxygen to produce a synthesis gas (syngas), which is then cleaned to rid of dust, tar, and acid gases. The second step reacts the synthesis gas with a catalyst in the FischerTropsch process, which converts the syngas into a range of hydrocarbon fuels such as ...
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Coal gasificationbased FischerTropsch (FT) synthesis processes, often termed " coaltoliquids " (CTL) plants, are complex integrated energy systems which typically exploit the waste heat from gas turbines and/or a number of process units in a Heat Recovery Steam Cycle (HRSC). Besides converting waste heat into electricity, the HRSC can also supply heat to endothermic processes in the ...
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The Bergius process for coal conversion to hydrocarbons requires temperatures above 450 °C6, pyrolysis of different polymers to pyrolysis oil is also typically carried out at similar temperatures7,8.
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Indirect liquefaction processes require first gasifying the solid feedstocks into a syngas. Therefore, while direct coal liquefaction (DCL) takes coal directly into a liquid phase, indirect coal liquefaction (ICL) consists of two major steps: (a) gasification to produce a synthesis gas (syngas); and (b) conversion of the carbon monoxide (CO) and hydrogen (H 2) in the syngas to a range of ...
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CoaltoLiquids. CoaltoLiquids (CTL) is a process of converting coal to fuels such as diesel or gas. For diesel, the process involves first building a plant to convert coal to gas and then another plant to covert the gas to a liquid. The resultant liquid fuel is known as synthetic fuel or synfuel. Synfuels are used as an alternative to oil ...
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A process for converting coals to principally hydrocarbon gases, by intimately contacting coals such as lignite coal with a reagent,, alkali metal polysulfides or alkali metal hydrosulfide, in the presence of steam, or a combination of steam and hydrogen, at temperatures between 65 to 450/sup 0/C. Liquid and gaseous hydrocarbons of preselected compositions may be produced; as it is well ...
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An example is the conversion of methane to chloroform using a chlorination reaction. Note that halogenating a hydrocarbon produces something that is not a hydrocarbon. It is a very common and useful process. Hydrocarbons with the same molecular formula but different structural formulae are called structural isomers.
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Liquefaction is the process of converting solid coal into liquid fuels. The main difference between naturally occurring petroleum fuels and coal is the deficiency of hydrogen in the latter: coal contains only about half the amount found in petroleum. Therefore, conversion of coal into liquid fuels involves the addition of hydrogen.
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Current status of CO2 capture from coal facilities. Marta G. Plaza, Covadonga Pevida, in New Trends in Coal Conversion, 2019 CO 2 capture in coaltoliquids industry. China has rich coal resources but lacks oil and gas; the coaltoliquids (CTL) technology rose as a consequence of increasing oil price, but regulators suspended new projects in 2008 after oil prices retreated and concerns ...
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direct and indirect. As the names imply, direct processes directly convert coalbased hydrocarbons into liquid fuels, while indirect processes use an intermediate process (gasification) to convert the coal into a gaseous fuel (syngas) before further refining the syngas into liquid fuels. Exhibit 21 gives a general overview of the processes ...
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The FischerTropsch process (FT) is a collection of chemical reactions that converts a mixture of carbon monoxide and hydrogen, known as syngas, into liquid reactions occur in the presence of metal catalysts, typically at temperatures of 150300 °C (302572 °F) and pressures of one to several tens of FischerTropsch process is an important reaction ...
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The primary process for FT is the Synthol Process; the schematic is shown in Figure The synthesis gas goes into the reactor at MPa of pressure and 315330°C. The product leaves the reactor where the catalyst is recovered, oils are removed by a hydrocarbon scrubber, and the tail gas recovered.
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4: CoaltoLiquids (CTL) Like GTL, coaltoliquids (CTL) fuels are produced by isolating the hydrocarbons in existing fossil fuels and converting them to a form of synthetic fuel that can be used in existing vehicles' engines. Manufacturers use two methods to make that conversion.
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